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A review of updated red phosphorus-based photocatalysts
Jizhou Jiang, Yanghanbin Zhang, Wei Sun, Jiahe Peng, Weilong Shi, Yang Qu, Enzhou Liu, Arramel, Zhiliang Jin
Composite Functional Materials ›› 2025, Vol. 1 ›› Issue (1) : 20250101.
PDF(12753 KB)
PDF(12753 KB)
A review of updated red phosphorus-based photocatalysts
Red phosphorus (RP), as a promising non-metallic photocatalyst, has garnered considerable attention due to its unique structural characteristics and exceptional optoelectronic properties. While previous reviews have explored RP-based photocatalysis, recent advancements in fabrication strategies, characterization techniques, and theoretical modeling have significantly reshaped the design, synthesis, and optimization of these materials. This review provides a comprehensive and critical evaluation of the latest progress in RP-based photocatalysts over the past five years, with a particular focus on strategies aimed at enhancing light harvesting capabilities, improving the separation and transport of photogenerated charge carriers, and ensuring long-term stability. Particular emphasis is placed on the role of innovative in-situ characterization techniques and density functional theory (DFT) simulations in elucidating the underlying photocatalytic mechanism across diverse applications, including photocatalytic hydrogen evolution, CO2 reduction, bacterial disinfection and organic pollutant degradation. Finally, this review highlights emerging challenges and forward-looking strategies to further boost the photocatalytic performance of RP-based systems, offering valuable insights for the rational design of next-generation non-metallic photocatalysts.
Red phosphorus / Photocatalysis / In-situ characterization / Density functional theory
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J.J., Y.Z. and Z.J. designed the proposal and wrote the manuscript. All authors have given approval to the final version of the manuscript.
The authors declare no competing financial interest.
This work is supported by the National Natural Science Foundation of China (62004143), the Key R&D Program of Hubei Province (2022BAA084), the Open Fund of the Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, and the Innovation Project of Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education (LCX202404).
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