PDF(4474 KB)
Research progress on Ti-based materials for MgH2 hydrogen storage systems
Huanhuan Zhang, Yanping Fan, Shuyan Guan, Wen-Gang Cui, Mingchang Zhang, Zhenglong Li, Yuhai Dou, Jiarui Yang, Zechao Zhuang, Zhenluo Yuan, Shiqian Zhao, Dingsheng Wang, Baozhong Liu, Hongge Pan
Composite Functional Materials ›› 2025, Vol. 1 ›› Issue (2) : 20250201.
PDF(4474 KB)
PDF(4474 KB)
Research progress on Ti-based materials for MgH2 hydrogen storage systems
Magnesium hydride (MgH2) as a solid-state hydrogen storage material has obtained intense attention in extensive research because of its high hydrogen-storage capacity, excellent reversibility, and relatively low cost. However, two primary obstacles of slow kinetics during hydrogenation/dehydrogenation process and high thermodynamic stability of Mg-H bond hinders the large-scale application of MgH2. Therefore, developing high-efficiency catalysts is necessary for hydrogen storage systems. Titanium (Ti) as an active element, shows promising in enhancing hydrogen storage activity and has been reported extensively. Herein, this review summarized the synthesis approaches, testing technology, and hydrogen storage performance of various Ti-based additives in detail. The structure-activity relationship of Ti-based materials was researched by combining experiment and DFT simulations. In particular, the focus is on the investigation of synthesis, characterization and reaction mechanism of various Ti-based additives. The real active sites and different reaction mechanisms during MgH2 hydrogen storage system are discussed. Finally, a summary and outlook were also presented. This review has the potential to guide the design of high-efficient catalysts and provide embedded guidance for future development and application of Mg-based materials in hydrogen storage system.
Hydrogen storage / Ti-based additives / Structure-activity relationship / Magnesium hydride
| [1] |
|
| [2] |
|
| [3] |
|
| [4] |
|
| [5] |
|
| [6] |
|
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
|
| [19] |
|
| [20] |
|
| [21] |
|
| [22] |
|
| [23] |
|
| [24] |
|
| [25] |
|
| [26] |
|
| [27] |
|
| [28] |
|
| [29] |
|
| [30] |
|
| [31] |
|
| [32] |
|
| [33] |
|
| [34] |
|
| [35] |
|
| [36] |
|
| [37] |
|
| [38] |
|
| [39] |
|
| [40] |
|
| [41] |
|
| [42] |
|
| [43] |
|
| [44] |
|
| [45] |
|
| [46] |
|
| [47] |
|
| [48] |
|
| [49] |
|
| [50] |
|
| [51] |
|
| [52] |
|
| [53] |
|
| [54] |
|
| [55] |
|
| [56] |
|
| [57] |
|
| [58] |
|
| [59] |
|
| [60] |
|
| [61] |
|
| [62] |
|
| [63] |
|
| [64] |
|
| [65] |
|
| [66] |
|
| [67] |
|
| [68] |
|
| [69] |
|
| [70] |
|
| [71] |
|
| [72] |
|
| [73] |
|
| [74] |
|
| [75] |
|
| [76] |
|
| [77] |
|
| [78] |
|
| [79] |
|
| [80] |
|
| [81] |
|
| [82] |
|
| [83] |
|
| [84] |
|
| [85] |
|
| [86] |
|
| [87] |
|
| [88] |
|
| [89] |
|
| [90] |
|
| [91] |
|
| [92] |
|
| [93] |
|
| [94] |
|
| [95] |
|
| [96] |
|
| [97] |
|
| [98] |
|
| [99] |
|
| [100] |
|
| [101] |
|
| [102] |
|
| [103] |
|
| [104] |
|
| [105] |
|
| [106] |
|
| [107] |
|
| [108] |
|
| [109] |
|
| [110] |
|
| [111] |
|
| [112] |
|
| [113] |
|
| [114] |
|
| [115] |
|
| [116] |
|
| [117] |
|
| [118] |
|
| [119] |
|
| [120] |
|
| [121] |
|
| [122] |
|
| [123] |
|
| [124] |
|
| [125] |
|
| [126] |
|
| [127] |
|
| [128] |
|
| [129] |
|
| [130] |
|
| [131] |
|
| [132] |
|
| [133] |
|
| [134] |
|
| [135] |
|
| [136] |
|
| [137] |
|
| [138] |
|
| [139] |
|
| [140] |
|
| [141] |
|
| [142] |
S Sumanth Dongre,
|
| [143] |
|
| [144] |
|
| [145] |
|
| [146] |
|
| [147] |
|
| [148] |
|
| [149] |
|
| [150] |
|
| [151] |
|
| [152] |
|
| [153] |
|
| [154] |
|
| [155] |
|
| [156] |
|
| [157] |
|
| [158] |
|
| [159] |
|
| [160] |
|
| [161] |
|
| [162] |
|
| [163] |
|
| [164] |
|
| [165] |
|
| [166] |
|
| [167] |
|
| [168] |
|
| [169] |
|
| [170] |
|
| [171] |
|
| [172] |
|
| [173] |
|
| [174] |
|
| [175] |
|
| [176] |
|
| [177] |
|
| [178] |
|
| [179] |
|
| [180] |
|
| [181] |
|
| [182] |
|
| [183] |
|
| [184] |
|
| [185] |
|
| [186] |
|
| [187] |
|
| [188] |
|
| [189] |
|
| [190] |
|
| [191] |
|
| [192] |
|
| [193] |
|
| [194] |
|
| [195] |
|
| [196] |
|
| [197] |
|
| [198] |
|
| [199] |
|
| [200] |
|
| [201] |
|
| [202] |
|
| [203] |
|
| [204] |
|
| [205] |
|
| [206] |
|
| [207] |
|
| [208] |
|
| [209] |
|
| [210] |
|
| [211] |
|
| [212] |
|
| [213] |
|
| [214] |
|
| [215] |
|
| [216] |
|
| [217] |
|
| [218] |
|
| [219] |
|
| [220] |
|
| [221] |
|
| [222] |
|
| [223] |
|
| [224] |
|
| [225] |
|
| [226] |
|
| [227] |
|
| [228] |
|
| [229] |
|
| [230] |
|
| [231] |
|
| [232] |
|
| [233] |
|
| [234] |
|
| [235] |
|
| [236] |
|
| [237] |
|
| [238] |
|
| [239] |
|
| [240] |
|
| [241] |
|
| [242] |
|
| [243] |
|
| [244] |
|
| [245] |
|
| [246] |
|
| [247] |
|
| [248] |
|
| [249] |
|
| [250] |
|
| [251] |
|
| [252] |
|
| [253] |
|
| [254] |
|
| [255] |
|
| [256] |
|
| [257] |
|
| [258] |
|
| [259] |
|
| [260] |
|
| [261] |
|
| [262] |
|
| [263] |
|
| [264] |
|
| [265] |
|
| [266] |
|
| [267] |
|
| [268] |
|
| [269] |
|
| [270] |
|
| [271] |
|
| [272] |
|
| [273] |
|
| [274] |
|
| [275] |
|
| [276] |
|
| [277] |
|
| [278] |
|
| [279] |
|
| [280] |
|
| [281] |
|
| [282] |
|
| [283] |
|
| [284] |
|
| [285] |
|
| [286] |
|
| [287] |
|
| [288] |
|
| [289] |
|
| [290] |
|
| [291] |
|
| [292] |
|
| [293] |
|
| [294] |
|
| [295] |
|
| [296] |
|
| [297] |
|
| [298] |
|
| [299] |
|
| [300] |
|
| [301] |
Noor Aliah Abdul Majid,
|
| [302] |
Mohamed Sherif El-Eskandarany. Metallic glassy Ti2Ni grain-growth inhibitor powder for enhancing the hydrogenation/dehydrogenation kinetics of MgH2, RSC Advances 2019, 9, 1036-1046. https://doi.org/10.1039/C8RA08200F.
|
| [303] |
|
| [304] |
|
| [305] |
|
| [306] |
|
| [307] |
|
| [308] |
|
| [309] |
|
| [310] |
|
| [311] |
|
| [312] |
|
| [313] |
|
| [314] |
|
| [315] |
|
| [316] |
|
| [317] |
|
| [318] |
|
| [319] |
|
| [320] |
Isabel Llamas Jansa.
|
| [321] |
|
| [322] |
Christian Bonatto Minella,
|
| [323] |
|
| [324] |
|
| [325] |
Nurul Nafiqah Itam Sulaiman. Muhammad Syarifuddin Yahya, Noratiqah Sazelee, Nurul Amirah Ali, Nurul Shafikah Mustafa, Muhammad Firdaus Asyraf Abdul Halim Yap, Mohammad Ismail. An investigation on the addition of SrTiO3 to the hydrogen storage properties of the 4MgH2-Li3AlH6 composite, International Journal of Energy Research 2022, 46, 8030-8041. https://doi.org/10.1002/er.7704.
|
| [326] |
|
| [327] |
|
| [328] |
|
| [329] |
|
| [330] |
|
| [331] |
|
| [332] |
|
| [333] |
|
| [334] |
|
| [335] |
|
| [336] |
|
| [337] |
|
| [338] |
Joshua Adedeji Bolarin,
|
| [339] |
|
| [340] |
|
| [341] |
|
| [342] |
|
| [343] |
|
| [344] |
|
| [345] |
|
| [346] |
|
| [347] |
|
| [348] |
|
| [349] |
|
| [350] |
|
| [351] |
|
| [352] |
|
This work was supported by the National Natural Science Foundation of China (22409052, 22409112, U22A20120, 52071135, 51871090 and U1804135), Henan Province Postdoctoral Research Projects (No. HN2025009), and High-level talent project of Henan University of Technology (No. 2023BS049). We thanked Sehrish Mehdi from The Women University Multan for the work in terms of language checking.
/
| 〈 |
|
〉 |