Decoupling mass transport from spin chemistry in electro-Fenton process under magnetic fields

Jing Li, Xiaoxiang Zhang, Yuxin Wei, Shan Qiu, Ignasi Sirés, Fengxia Deng

Compos Funct Mater ›› 2026

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Compos Funct Mater ›› 20260050002 2026 DOI: 10.63823/20260050002
Review article

Decoupling mass transport from spin chemistry in electro-Fenton process under magnetic fields

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Abstract

Electro-Fenton (EF) is one of the most effective processes for treating organic pollutants in water. However, its performance is often restricted by mass transport limitations and slow catalytic reactions. While recent reviews have summarized various strategies to enhance the EF process performance, a focused analysis separating the physical magnetohydrodynamic (MHD) effect on mass transport from the quantum spin-chemistry effect on reaction kinetics-one of the most promising enhancement routes-has not yet been established. Here, this gap is addressed by developing a framework including the four key species of the EF systems: the Fe2+/Fe3+ redox couple, the reactants (H+ and O2), and the electrons supplied. On this basis, the influence of magnetic fields on each species is examined, clearly distinguishing MHD-driven mass transport from spin-chemistry effects on intrinsic kinetics. This distinction helps resolve ongoing mechanistic debates and provides practical guidance for designing advanced magnetically assisted water treatment technologies.

Key words

Advanced oxidation processes (AOPs) / Electro-Fenton (EF) / magnetic field / magnetohydrodynamics (MHD) / mechanistic study / spin chemistry

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Jing Li , Xiaoxiang Zhang , Yuxin Wei , et al . Decoupling mass transport from spin chemistry in electro-Fenton process under magnetic fields[J]. Composite Functional Materials. 2026 https://doi.org/10.63823/20260050002

References

[1]
Enric Brillas, Ignasi Sirés, Mehmet A. Oturan. Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry. Chemical Reviews 2009, 109, 6570-6631. https://doi.org/10.1021/cr900136g
[2]
Mehmet A. Oturan, Jean-Jacques Aaron. Advanced oxidation processes in Water/Wastewater treatment: principles and applications. a review. Critical Reviews in Environmental Science and Technology 2014, 44, 2577-2641. https://doi.org/10.1080/10643389.2013.829765
[3]
Xixi Wang, Chao Xu, Yuan Zhu, Chuan Zhou, Yang Yang, Jie Miao, Wei Zhou, Zongping Shao. The recent progress of cathode materials for heterogeneous electro-Fenton reactions. Surfaces and Interfaces 2024, 44, 103820. https://doi.org/10.1016/j.surfin.2023.103820
[4]
Qizhan Zhang, Minghua Zhou, Xuedong Du, Pei Su, Wenyang Fu, Ge Song. Highly efficient dual-cathode electro-Fenton process without aeration at a wide pH range: simultaneously enhancing Fe(II) regeneration and mineralization efficiency. Chemical Engineering Journal 2022, 429, 132436. https://doi.org/10.1016/j.cej.2021.132436
[5]
Akbar Eskandarpour, Kensuke Sassa, Yoshiyuki Bando, Masazumi Okido, Shigeo Asai. Magnetic removal of phosphate from wastewater using schwertmannite. MATERIALS TRANSACTIONS 2006, 47, 1832-1837. https://doi.org/10.2320/matertrans.47.1832
[6]
Baojian Jing, Qiwei Zhang, Minghui Liu, Shilin Yang, Jiayu Zhang, Shan Qiu, Ignasi Sirés, Fengxia Deng. Magnetically-altered eg-orbital occupancy to boost the two-electron oxygen reduction electrocatalysis for faster water decontamination. Applied Catalysis B: Environment and Energy 2025, 369, 125149. https://doi.org/10.1016/j.apcatb.2025.125149
[7]
Caio Machado Fernandes, Aila O. Santos, Vanessa S. Antonin, João Paulo C. Moura, Aline B. Trench, Odivaldo C. Alves, Yutao Xing, Júlio César M. Silva, Mauro C. Santos. Magnetic field-enhanced oxygen reduction reaction for electrochemical hydrogen peroxide production with different cerium oxide nanostructures. Chemical Engineering Journal 2024, 488, 150947. https://doi.org/10.1016/j.cej.2024.150947
[8]
Ulrich E. Steiner, Thomas Ulrich. Magnetic field effects in chemical kinetics and related phenomena. Chemical Reviews 1989, 89, 51-147. https://doi.org/10.1021/cr00091a003
[9]
Anatoly L. Buchachenko, Vitaly L. Berdinsky. Electron spin catalysis. Chemical Reviews 2002, 102, 603-612. https://doi.org/10.1021/cr010370l
[10]
Xiao Long Hao, Lu Yi Zou, Guang Sheng Zhang, Yi Bo Zhang. Magnetic field assisted Fenton reactions for the enhanced degradation of methyl blue. Chinese Chemical Letters 2009, 20, 99-101. https://doi.org/10.1016/j.cclet.2008.09.058
[11]
Songzhu Luo, Kamal Elouarzaki, Zhichuan J. Xu. Electrochemistry in magnetic fields. Angewandte Chemie International Edition 2022, 61, e202203564. https://doi.org/10.1002/anie.202203564
[12]
Cunyuan Gao, Bin Cai. Spin effects in optimizing electrochemical applications. ACS Materials Au 2025, 5, 253-267. https://doi.org/10.1021/acsmaterialsau.4c00092
[13]
Caio Machado Fernandes, João Paulo C. Moura, Aline B. Trench, Odivaldo C. Alves, Yutao Xing, Marcos R.V. Lanza, Júlio César M. Silva, Mauro C. Santos. Magnetic field-enhanced two-electron oxygen reduction reaction using CeMnCo nanoparticles supported on different carbonaceous matrices. Materials Today Nano 2024, 28, 100524. https://doi.org/10.1016/j.mtnano.2024.100524
[14]
Zhiqiao He, Chao Gao, Mengqian Qian, Yuanqiao Shi, Jianmeng Chen, Shuang Song. Electro-Fenton process catalyzed by Fe3O4 magnetic nanoparticles for degradation of C.I. reactive blue 19 in aqueous solution: operating conditions, influence, and mechanism. Industrial & Engineering Chemistry Research 2014, 53, 3435-3447. https://doi.org/10.1021/ie403947b
[15]
Xiaodong Ma, Tiantong Rao, Mingchen Zhao, Zhiwei Jia, Gengbo Ren, Jingyang Liu, Haiwei Guo, Zhineng Wu, Haijiao Xie. A novel induced zero-valent iron electrode for in-situ slow release of Fe2+ to effectively trigger electro-Fenton oxidation under neutral pH condition: advantages and mechanisms. Separation and Purification Technology 2022, 283, 120160. https://doi.org/10.1016/j.seppur.2021.120160
[16]
Fengxia Deng, Hugo Olvera-Vargas, Minghua Zhou, Shan Qiu, Ignasi Sirés, Enric Brillas. Critical review on the mechanisms of Fe2+ regeneration in the electro-Fenton process: fundamentals and boosting strategies. Chemical Reviews 2023, 123, 4635-4662. https://doi.org/10.1021/acs.chemrev.2c00684
[17]
Zhengjie Chen, Xiaoning Li, Hao Ma, Yuwei Zhang, Jing Peng, Tianyi Ma, Zhenxiang Cheng, Jose Gracia, Yuanmiao Sun, Zhichuan J Xu. Spin-dependent electrocatalysis. National Science Review 2024, 11, nwae314. https://doi.org/10.1093/nsr/nwae314
[18]
Sichen Huo, Xinyu Wang, Yanjie Chen, Hang Yue, Li Li, Jinlong Zou. Spin effects in electrocatalysis: mechanisms, catalyst engineering, modulation, and applications. Materials Science and Engineering: R: Reports 2025, 164, 100967. https://doi.org/10.1016/j.mser.2025.100967
[19]
Kyunghee Chae, Nur Aqlili Riana Che Mohamad, Jeonghyeon Kim, Dong-Il Won, Zhiqun Lin, Jeongwon Kim, Dong Ha Kim. The promise of chiral electrocatalysis for efficient and sustainable energy conversion and storage: a comprehensive review of the CISS effect and future directions. Chemical Society Reviews 2024, 53, 9029-9058. https://doi.org/10.1039/d3cs00316g
[20]
Vivien Gatard, Jonathan Deseure, Marian Chatenet. Use of magnetic fields in electrochemistry: a selected review. Current Opinion in Electrochemistry 2020, 23, 96-105. https://doi.org/10.1016/j.coelec.2020.04.012
[21]
Dibyendu Barik, Utkarsh Utkarsh, Koyel Banerjee Ghosh. Spin-controlled electrocatalysis: an out-of-the-box strategy for the advancement of electrochemical water splitting. Chemical Communications 2025, 61, 6226-6245. https://doi.org/10.1039/D5CC01305D
[22]
Chiara Biz, José Gracia, Mauro Fianchini. Review on magnetism in catalysis: from theory to PEMFC applications of 3d metal Pt-based alloys. International Journal of Molecular Sciences 2022, 23, 14768. https://doi.org/10.3390/ijms232314768
[23]
Oleg Lioubashevski, Eugenii Katz, Itamar Willner. Magnetic field effects on electrochemical processes: a theoretical hydrodynamic model. The Journal of Physical Chemistry B 2004, 108, 5778-5784. https://doi.org/10.1021/jp037785q
[24]
Wenliang Wang, Tao Yu, Ying Cheng, Xuefei Lei, Biao Wang, Rui Guo, Xuanwen Liu, Junhua You, Xiaoxue Wang, Hangzhou Zhang. Field-assisted metal-air batteries: recent progress, mechanisms, and challenges. Nano Energy 2024, 125, 109550. https://doi.org/10.1016/j.nanoen.2024.109550
[25]
Melissa C. Weston, Matthew D. Gerner, Ingrid Fritsch.Magnetic fields for fluid motion. Analytical Chemistry 2010, 82, 3411-3418. https://doi.org/10.1021/ac901783n
[26]
Ryoichi Morimoto, Miki Miura, Atsushi Sugiyama, Makoto Miura, Yoshinobu Oshikiri, Iwao Mogi, Satoshi Takagi, Yusuke Yamauchi, Ryoichi Aogaki. Theory of microscopic electrodeposition under a uniform parallel magnetic field- 2. suppression of 3D nucleation by micro-MHD flow. Journal of Electroanalytical Chemistry 2019, 847, 113255. https://doi.org/10.1016/j.jelechem.2019.113255
[27]
Dominik Baczyzmalski, Franziska Karnbach, Xuegeng Yang, Gerd Mutschke, Margitta Uhlemann, Kerstin Eckert, Christian Cierpka. On the electrolyte convection around a hydrogen bubble evolving at a microelectrode under the influence of a magnetic field. Journal of The Electrochemical Society 2016, 163, E248-E257. https://doi.org/10.1149/2.0381609jes
[28]
Tomoya Kanno, Kenji Ohoyama, Hajime Nakada, Yuto Fukui, Kota Yamakawa, Shota Hoshi, Motoki Takano, Yodai Kobayashi, Yuka Tomimatsu, Shingo Takahashi, Takayuki Oku, Takuya Okudaira, Ryuju Kobayashi, Shusuke Takada, Masahide Harada, Kenichi Oikawa, Yasuhiro Inamura, Toetsu Shishido, Keisuke Sato, Koichi Hayashi. Development of instruments for imaging of local magnetic structure by magnetic neutron holography. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 2024, 1064, 169349. https://doi.org/10.1016/j.nima.2024.169349
[29]
Magne Waskaas. On the origin of the magnetic concentration gradient force and its interaction mechanisms with mass transfer in paramagnetic electrolytes. Fluids 2021, 6, 114. https://doi.org/10.3390/fluids6030114
[30]
Yuankui Sun, Xiaohong Guan, Jianmin Wang, Xiaoguang Meng, Chunhua Xu, Gongming Zhou. Effect of weak magnetic field on arsenate and arsenite removal from water by zerovalent iron: an XAFS investigation. Environmental Science & Technology 2014, 48, 6850-6858. https://doi.org/10.1021/es5003956
[31]
F.L. Rivera, F.J. Recio, F.J. Palomares, J. Sánchez-Marcos, N. Menéndez, E. Mazarío, P. Herrasti. Fenton-like degradation enhancement of methylene blue dye with magnetic heating induction. Journal of Electroanalytical Chemistry 2020, 879, 114773. https://doi.org/10.1016/j.jelechem.2020.114773
[32]
Zemin Sun, Liu Lin, Jinlu He, Dajie Ding, Tongyue Wang, Jie Li, Mingxuan Li, Yicheng Liu, Yayin Li, Mengwei Yuan, Binbin Huang, Huifeng Li, Genban Sun. Regulating the spin state of FeIII enhances the magnetic effect of the molecular catalysis mechanism. Journal of the American Chemical Society 2022, 144, 8204-8213. https://doi.org/10.1021/jacs.2c01153
[33]
Michelle M. Scherer, Kathleen M. Johnson, John C. Westall, Paul G. Tratnyek. Mass transport effects on the kinetics of nitrobenzene reduction by iron metal. Environmental Science & Technology 2001, 35, 2804-2811. https://doi.org/10.1021/es0016856
[34]
Priscila Vensaus, Yunchang Liang, Jean-Philippe Ansermet, Galo J. A. A. Soler-Illia, Magalí Lingenfelder. Enhancement of electrocatalysis through magnetic field effects on mass transport. Nature Communications 2024, 15, 2867. https://doi.org/10.1038/s41467-024-46980-8
[35]
Yu Xia, Weiyuan Chen, Priscila Vensaus, Yiwei Sun, Yunchang Liang, Magalí Lingenfelder, Wenbo Ju. Quantifying the reduction of OER overpotential on magnetic electrocatalysts under magnetic fields. Small Methods 2025, 9, e01068. https://doi.org/10.1002/smtd.202501068
[36]
Dawei Wang, Tingyue Chen, Yilan Jiang, Xinyang Cai, Yingying Li, Yuanyuan Chen, Guang Yang, Feng Pan. Alternating magnetic field accelerates the transformation between Fe(II) and Fe(III) of Fe@NiFe2O4 in a Fenton-like process. Journal of Environmental Engineering 2024, 150, 04024020. https://doi.org/10.1061/joeedu.eeeng-7593
[37]
Karina E. Trotsenko, Ilia D. Shabalkin, Elena F. Krivoshapkina, Pavel V. Krivoshapkin. Alternating magnetic field-enhanced electrocatalysis: mechanisms, synergistic effects, and future perspectives. Nano Energy 2026, 147, 111573. https://doi.org/10.1016/j.nanoen.2025.111573
[38]
Huan-Yang Chen, Yen-Fang Lin, Chia-Chun Chen. Why the reactive oxygen species of the Fenton reaction switches from oxoiron(IV) species to hydroxyl radical in phosphate buffer solutions? A computational rationale. ACS Catalysis 2019, 9, 8875-8885. https://doi.org/10.1021/acscatal.9b02148
[39]
Naroa Kajarabille, Gladys O. Latunde-Dada. Programmed cell-death by ferroptosis: antioxidants as mitigators. International Journal of Molecular Sciences 2019, 20, 4968. https://doi.org/10.3390/ijms20194968
[40]
Xunguo Gong, Zhenzhen Jiang, Wei Zeng, Ce Hu, Xingfang Luo, Wen Lei, Cailei Yuan. Alternating magnetic field induced magnetic heating in ferromagnetic cobalt single-atom catalysts for efficient oxygen evolution reaction. Nano Letters 2022, 22, 9411-9417. https://doi.org/10.1021/acs.nanolett.2c03359
[41]
Yongwen Sun, Hong Lv, Han Yao, Yuanfeng Gao, Cunman Zhang. Magnetic field‐assisted electrocatalysis: mechanisms and design strategies. Carbon Energy 2024, 6, e575. https://doi.org/10.1002/cey2.575
[42]
Wentao Xiang, Yongyu Lu, Hongzhang Wang, Xuyang Sun, Sen Chen, Zhizhu He, Jing Liu.Liquid-metal-based magnetic fluids. Nature Reviews Materials 2024, 9, 433-449. https://doi.org/10.1038/s41578-024-00679-w
[43]
Qian Luo, Zhenchang Yin, Zhengfeng Hu, Wei Zhang, Yu Zhang, Huimin Huang, Zhihui Chen, Junjie Xu, Rongwu Mei. Magnetic intensification of Fenton processes using superconducting technology for enhanced treatment of printing and dyeing wastewater: mechanisms and applications. Water 2025, 17, 2686. https://doi.org/10.3390/w17182686
[44]
Zahra Heidari, Rasool Pelalak, Minghua Zhou. A critical review on the recent progress in application of electro-Fenton process for decontamination of wastewater at near-neutral pH. Chemical Engineering Journal 2023, 474, 145741. https://doi.org/10.1016/j.cej.2023.145741
[45]
M. Uhlemann, A. Krause, A. Gebert. Effect of a magnetic field on the local pH value in front of the electrode surface during electrodeposition of Co. Journal of Electroanalytical Chemistry 2005, 577, 19-24. https://doi.org/10.1016/j.jelechem.2004.11.009
[46]
Malathy Ramalingam, Karuppasamy Narayanan, Arivoli Masilamani, Parthiban Kathirvel, Gunasekaran Murali, Nikolai Ivanovich Vatin. Influence of magnetic water on concrete properties with different magnetic field exposure times. Materials 2022, 15, 4291. https://doi.org/10.3390/ma15124291
[47]
Peter Dunne, J. M. D. Coey. Influence of a magnetic field on the electrochemical double layer. The Journal of Physical Chemistry C 2019, 123, 24181-24192. https://doi.org/10.1021/acs.jpcc.9b07534
[48]
Junjian Zhou, Zhiyuan Li, Qi Wang, Na Li, Xu Li, Yana Wang, Weili Song. Brief review of external physical field-boosted low-temperature electrodeposition for metals and alloys. International Journal of Minerals, Metallurgy and Materials 2025, 32, 992-1007. https://doi.org/10.1007/s12613-024-3035-0
[49]
Yuanyuan Zhang, Ce Liang, Jie Wu, Han Liu, Bin Zhang, Zaixing Jiang, Siwei Li, Ping Xu. Recent advances in magnetic field-enhanced electrocatalysis. ACS Applied Energy Materials 2020, 3, 10303-10316. https://doi.org/10.1021/acsaem.0c02104
[50]
Emil Chibowski, Aleksandra Szcześ, Lucyna Hołysz. Influence of magnetic field on evaporation rate and surface tension of water. Colloids and Interfaces 2018, 2, 68. https://doi.org/10.3390/colloids2040068
[51]
Ran Cai, Hongwei Yang, Jinsong He, Wanpeng Zhu. The effects of magnetic fields on water molecular hydrogen bonds. Journal of Molecular Structure 2009, 938, 15-19. https://doi.org/10.1016/j.molstruc.2009.08.037
[52]
V. Jelle Lagerweij, Sana Bougueroua, Parsa Habibi, Poulumi Dey, Marie-Pierre Gaigeot, Othonas A. Moultos, Thijs J. H. Vlugt. From Grotthuss transfer to conductivity: machine learning molecular dynamics of aqueous KOH. The Journal of Physical Chemistry B 2025, 129, 6093-6099. https://doi.org/10.1021/acs.jpcb.5c03199
[53]
Ankita Dutta, Themis Lazaridis. Classical models of hydroxide for proton hopping simulations. The Journal of Physical Chemistry B 2024, 128, 12161-12170. https://doi.org/10.1021/acs.jpcb.4c05499
[54]
Ali Hassanali, Federico Giberti, Jérôme Cuny, Thomas D. Kühne, Michele Parrinello. Proton transfer through the water gossamer. Proceedings of the National Academy of Sciences 2013, 110, 13723-13728. https://doi.org/10.1073/pnas.1306642110
[55]
Onno van der Heijden, Sunghak Park, Jordy J. J. Eggebeen, Marc T. M. Koper. Non‐Kinetic effects convolute activity and Tafel analysis for the alkaline oxygen evolution reaction on NiFeOOH electrocatalysts. Angewandte Chemie International Edition 2023, 62, e202216477. https://doi.org/10.1002/anie.202216477
[56]
Ge Song, Minghua Zhou, Xuedong Du, Pei Su, Jieru Guo. Mechanistic insight into the heterogeneous electro-Fenton/Sulfite process for ultraefficient degradation of pollutants over a wide pH range. ACS ES&T Water 2021, 1, 1637-1647. https://doi.org/10.1021/acsestwater.1c00123
[57]
Shi-Lin Xu, Wei Wang, Yi Song, Rui Tang, Zhen-Hu Hu, Xiao Zhou, Han-Qing Yu. Expanding the pH range of Fenton-like reactions for pollutant degradation: the impact of acidic microenvironments. Water Research 2025, 270, 122851. https://doi.org/10.1016/j.watres.2024.122851
[58]
Yanbo Li, Guohang Fu, Chao Miao, Jingyan Liu, Jianrong Zeng, Guohua Zhao. Local acidic microenvironment construction via alternating current electro-Fenton process for green efficient water purification under neutral conditions. Environmental Science & Technology 2025, 59, 16392-16401. https://doi.org/10.1021/acs.est.5c03443
[59]
Lan Luo, Liang Xu, Qingyu Wang, Qiwei Shi, Huan Zhou, Zhenhua Li, Mingfei Shao, Xue Duan. Recent advances in external fields-enhanced electrocatalysis. Advanced Energy Materials 2023, 13, 2301276. https://doi.org/10.1002/aenm.202301276
[60]
Zhengmei Zhang, Lei Jia, Tong Li, Jinmei Qian, Xiaolei Liang, Desheng Xue, Daqiang Gao. In-situ magnetic field enhanced performances in ferromagnetic FeCo2O4 nanofibers-based rechargeable zinc-air batteries. Journal of Energy Chemistry 2023, 78, 447-453. https://doi.org/10.1016/j.jechem.2022.12.038
[61]
Yuanyuan Zhang, Ping Guo, Siwei Li, Jianmin Sun, Wei Wang, Bo Song, Xiaoxuan Yang, Xianjie Wang, Zaixing Jiang, Gang Wu, Ping Xu. Magnetic field assisted electrocatalytic oxygen evolution reaction of nickel-based materials. Journal of Materials Chemistry A 2022, 10, 1760-1767. https://doi.org/10.1039/d1ta09444k
[62]
Zheng Zeng, Yiyang Liu, Wendi Zhang, Harish Chevva, Jianjun Wei. Improved supercapacitor performance of MnO2-electrospun carbon nanofibers electrodes by mt magnetic field. Journal of Power Sources 2017, 358, 22-28. https://doi.org/10.1016/j.jpowsour.2017.05.008
[63]
Xu Zhao, Hang Ren, Long Luo. Gas bubbles in electrochemical gas evolution reactions. Langmuir 2019, 35, 5392-5408. https://doi.org/10.1021/acs.langmuir.9b00119
[64]
Andrea Angulo, Peter van der Linde, Han Gardeniers, Miguel Modestino, David Fernández Rivas. Influence of bubbles on the energy conversion efficiency of electrochemical reactors. Joule 2020, 4, 555-579. https://doi.org/10.1016/j.joule.2020.01.005
[65]
H. Vogt, R.J. Balzer. The bubble coverage of gas-evolving electrodes in stagnant electrolytes. Electrochimica Acta 2005, 50, 2073-2079. https://doi.org/10.1016/j.electacta.2004.09.025
[66]
Dámaris Fernández, Milena Martine, Aaron Meagher, Matthias E. Möbius J.M.D. Coey. Stabilizing effect of a magnetic field on a gas bubble produced at a microelectrode. Electrochemistry Communications 2012, 18, 28-32. https://doi.org/10.1016/j.elecom.2012.01.016
[67]
Tom Weier, Dominik Baczyzmalski, Julian Massing, Steffen Landgraf, Christian Cierpka. The effect of a Lorentz-force-driven rotating flow on the detachment of gas bubbles from the electrode surface. International Journal of Hydrogen Energy 2017, 42, 20923-20933. https://doi.org/10.1016/j.ijhydene.2017.07.034
[68]
Lorena M.A. Monzon J.M.D. Coey. a mini-review. Magnetic fields in electrochemistry: the Kelvin force. Electrochemistry Communications 2014, 42, 42-45. https://doi.org/10.1016/j.elecom.2014.02.005
[69]
Chieh-Wei Chung, Jyun-Yau Huang, Jing-Guan Liang, Linda Iffland, Loise Ann Dayao, Dinesh Kumar Dhanthala Chittibabu, Chong-Chi Chi, Jeng-Lung Chen, Ting-Shan Chan, Chi-Liang Chen, Ying-Rui Lu, Chieh-Cheng Huang, Ho-Hsiu Chou, Zong-Hong Lin, Ying-Chieh Chen, Ming-Yen Lu, Hsin-Tsung Chen, Ulf-Peter Apfel, Yei-Chen Lai, Tsai-Te Lu. Magneto-voltaic activity of single-atom iron on reduced graphene oxide for magneto-catalytic conversion of H2O2 into O2. Chemical Science 2026, 17, 1073-1097. https://doi.org/10.1039/d5sc05275k
[70]
Xiao Ren, Tianze Wu, Yuanmiao Sun, Yan Li, Guoyu Xian, Xianhu Liu, Chengmin Shen, Jose Gracia, Hong-Jun Gao, Haitao Yang, Zhichuan J. Xu. Spin-polarized oxygen evolution reaction under magnetic field. Nature Communications 2021, 12, 2608. https://doi.org/10.1038/s41467-021-22865-y
[71]
Haiping Pan, XingXing Jiang, Xikui Wang, Qinglong Wang, Mingkui Wang, Yan Shen. Effective magnetic field regulation of the radical pair spin states in electrocatalytic CO2 reduction. The Journal of Physical Chemistry Letters 2020, 11, 48-53. https://doi.org/10.1021/acs.jpclett.9b03146
[72]
Paul V. Möllers, Benjamin Göhler, Helmut Zacharias. Chirality induced spin selectivity - the photoelectron view. Israel Journal of Chemistry 2022, 62, e202200062. https://doi.org/10.1002/ijch.202200062
[73]
Benjamin D. Ravetz, Nicholas E. S. Tay, Candice L. Joe, Melda Sezen-Edmonds, Michael A. Schmidt, Yichen Tan, Jacob M. Janey, Martin D. Eastgate, Tomislav Rovis. Development of a platform for near-infrared photoredox catalysis. ACS Central Science 2020, 6, 2053-2059. https://doi.org/10.1021/acscentsci.0c00948
[74]
Meng Liu, Jingyi Zhu, Guohui Zhao, Yuxuan Li, Yupeng Yang, Kaimin Gao, Kaifeng Wu. Coherent manipulation of photochemical spin-triplet formation in quantum dot-molecule hybrids. Nature Materials 2025, 24, 260-267. https://doi.org/10.1038/s41563-024-02061-1
[75]
Paul V. Möllers, Jimeng Wei, Soma Salamon, Manfred Bartsch, Heiko Wende, David H. Waldeck, Helmut Zacharias. Spin-polarized photoemission from chiral CuO catalyst thin films. ACS Nano 2022, 16, 12145-12155. https://doi.org/10.1021/acsnano.2c02709
[76]
Dongquan Peng, Ce Hu, Xingfang Luo, Jinli Huang, Yan Ding, Wenda Zhou, Hang Zhou, Yong Yang, Ting Yu, Wen Lei, Cailei Yuan. Electrochemical reconstruction of NiFe/NiFeOOH superparamagnetic Core/Catalytic shell heterostructure for magnetic heating enhancement of oxygen evolution reaction (small 3/2023). Small 2023, 19, 2370014. https://doi.org/10.1002/smll.202370014
[77]
Thi Ngoc Ha Nguyen, Georgeta Salvan, Olav Hellwig, Yossi Paltiel, Lech Thomasz Baczewski, Christoph Tegenkamp. The mechanism of the molecular CISS effect in chiral nano-junctions. Chemical Science 2024, 15, 14905-14912. https://doi.org/10.1039/d4sc04435e
[78]
Priscila Vensaus, Yunchang Liang, Jean-Philippe Ansermet, Jonas Fransson, Magalí Lingenfelder. Spin-polarized electron transport promotes the oxygen reduction reaction. ACS Nano 2025, 19, 38709-38715. https://doi.org/10.1021/acsnano.5c14333
[79]
Zhi Fang, Wanting Zhao, Tong Shen, Daping Qiu, Yucheng Lv, Xinmei Hou, Yanglong Hou.Spin-modulated oxygen electrocatalysis. Precision Chemistry 2023, 1, 395-417. https://doi.org/10.1021/prechem.3c00059
[80]
Haoyun Bai, Di Liu, Pengfei Zhou, Jinxian Feng, Xulei Sui, Yunhao Lu, Hongchao Liu, Hui Pan. Spin evolution and flip in the oxygen reduction reaction: a theoretical study of Cu(Ni)XP2S6( X = in, bi and cr). Journal of Materials Chemistry A 2022, 10, 25262-25271. https://doi.org/10.1039/d2ta07188f
[81]
Bernd Ensing, Francesco Buda, Evert Jan Baerends. Fenton-like chemistry in water: oxidation catalysis by Fe(III) and H2O2. The Journal of Physical Chemistry A 2003, 107, 5722-5731. https://doi.org/10.1021/jp0267149
[82]
U. Till, C.R. Timmel, B. Brocklehurst, P.J. Hore. The influence of very small magnetic fields on radical recombination reactions in the limit of slow recombination. Chemical Physics Letters 1998, 298, 7-14. https://doi.org/10.1016/s0009-2614(98)01158-0
[83]
Chuang Zhang, Chen Ye, Jiannian Yao, Li-Zhu Wu.Spin-related excited-state phenomena in photochemistry. National Science Review 2024, 11, nwae244. https://doi.org/10.1093/nsr/nwae244
[84]
Chih-Hsiang Liao, Shyh-Fang Kang, Fu-An Wu. Hydroxyl radical scavenging role of chloride and bicarbonate ions in the H2O2/UV process. Chemosphere 2001, 44, 1193-1200. https://doi.org/10.1016/s0045-6535(00)00278-2
[85]
Jiaying Xiao, Sufang Guo, Dong Wang, Qi An. Fenton‐Like reaction: recent advances and new trends. Chemistry - A European Journal 2024, 30, e202304337. https://doi.org/10.1002/chem.202304337
[86]
Derek B. Rice, Deniz Wong, Thomas Weyhermüller, Frank Neese, Serena DeBeer. The spin-forbidden transition in iron(IV)-oxo catalysts relevant to two-state reactivity. Science Advances 2024, 10, eado1603. https://doi.org/10.1126/sciadv.ado1603
[87]
Yuanfang Lin, Ying Wang, Zongling Weng, Yang Zhou, Siqi Liu, Xinwen Ou, Xing Xu, Yanpeng Cai, Jin Jiang, Bin Han, Zhifeng Yang. Coordination engineering of heterogeneous high-valent Fe(IV)-oxo for safe removal of pollutants via powerful Fenton-like reactions. Nature Communications 2024, 15, 10032. https://doi.org/10.1038/s41467-024-54225-x
[88]
R. Naaman, David H. Waldeck. Chiral-induced spin selectivity effect. The Journal of Physical Chemistry Letters 2012, 3, 2178-2187. https://doi.org/10.1021/jz300793y
[89]
Fan He, Eleanor Gillette, Xingxing Wang, Aila Huxford, Chuanxiao Xiao, Yong Yan, Matthew C. Beard, Jing Gu. Spin-polarized oxygen evolution reaction enabled by chiral molecules coupled with ferromagnetic electrocatalysts. ACS Applied Materials & Interfaces 2025, 17, 69389-69397. https://doi.org/10.1021/acsami.5c18273
[90]
Wenqiang Gao, Rui Peng, Yuying Yang, Xiaolei Zhao, Chao Cui, Xiaowen Su, Wei Qin, Ying Dai, Yandong Ma, Hong Liu, Yuanhua Sang. Electron spin polarization-enhanced photoinduced charge separation in ferromagnetic ZnFe2O4. ACS Energy Letters 2021, 6, 2129-2137. https://doi.org/10.1021/acsenergylett.1c00682
[91]
Timothy Moorsom, May Wheeler, Taukeer Mohd Khan, Fatma Al Ma'Mari, Christian Kinane, Sean Langridge, David Ciudad, Amílcar Bedoya-Pinto, Luis Hueso, Gilberto Teobaldi, Vlado K. Lazarov, Daniel Gilks, Gavin Burnell, Bryan J. Hickey, Oscar Cespedes. Spin-polarized electron transfer in ferromagnet/C60 interfaces. Physical Review B 2014, 90, 125311. https://doi.org/10.1103/physrevb.90.125311
[92]
Deepak Khurana, Rasmus H. Jensen, Rakshyakar Giri, Juanita Bocquel, Ulrik L. Andersen, Kirstine Berg-Sørensen, Alexander Huck. Sensing of magnetic field effects in radical-pair reactions using a quantum sensor. Physical Review Research 2024, 6, 013218. https://doi.org/10.1103/physrevresearch.6.013218
[93]
Christine Bellouard, Sanghoon Kim, Jaafar Ghanbaja, Robert Wojcieszak, Nadia Canilho, Andreea Pasc. Unraveling oxidation and spin states of a single Fe-based meso-macroporous silica catalyst in Fenton-like reaction by magnetic measurements. The Journal of Physical Chemistry C 2024, 128, 8449-8457. https://doi.org/10.1021/acs.jpcc.4c00816
[94]
Krysti L. Knoche Gupta, Heung Chan Lee, Johna Leddy. Magnetoelectrocatalysis: evidence from the hydrogen evolution reaction. ACS Physical Chemistry Au 2024, 4, 148-159. https://doi.org/10.1021/acsphyschemau.3c00039
[95]
Shuzhao Pei, Shijie You, Jun Ma, Xiaodong Chen, Nanqi Ren. Electron spin resonance evidence for electro-generated hydroxyl radicals. Environmental Science & Technology 2020, 54, 13333-13343. https://doi.org/10.1021/acs.est.0c05287
[96]
Aditya Prajapati, Christopher Hahn, Inez M. Weidinger, Yanmei Shi, Yonghyuk Lee, Anastassia N. Alexandrova, David Thompson, Simon R. Bare, Shuai Chen, Shuai Yan, Nikolay Kornienko. Best practices for in-situ and operando techniques within electrocatalytic systems. Nature Communications 2025, 16, 2593. https://doi.org/10.1038/s41467-025-57563-6
[97]
Graeme Henkelman, Hannes Jónsson. Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points. The Journal of Chemical Physics 2000, 113, 9978-9985. https://doi.org/10.1063/1.1323224
[98]
Oscar M. Cornejo, Ignasi Sirés, José L. Nava. Cathodic generation of hydrogen peroxide sustained by electrolytic O2 in a rotating cylinder electrode (RCE) reactor. Electrochimica Acta 2022, 404, 139621. https://doi.org/10.1016/j.electacta.2021.139621
[99]
Anu Gupta, Anil Kumar, Deb Kumar Bhowmick, Claudio Fontanesi, Yossi Paltiel, Jonas Fransson, Ron Naaman. Does coherence affect the multielectron oxygen reduction reaction? The Journal of Physical Chemistry Letters 2023, 14, 9377-9384. https://doi.org/10.1021/acs.jpclett.3c02594
[100]
Xiao Zhang, Xunhua Zhao, Peng Zhu, Zachary Adler, Zhen-Yu Wu, Yuanyue Liu, Haotian Wang. Electrochemical oxygen reduction to hydrogen peroxide at practical rates in strong acidic media. Nature Communications 2022, 13, 2880. https://doi.org/10.1038/s41467-022-30337-0
[101]
Hélène Monteil, Nihal Oturan, Yoan Péchaud, Mehmet A. Oturan. Efficient removal of diuretic hydrochlorothiazide from water by electro-Fenton process using BDD anode: a kinetic and degradation pathway study. Environmental Chemistry 2019, 16, 613-621. https://doi.org/10.1071/en19121
[102]
Hongbo Liu, Liang-ming Pan, Haojie Huang, Qijun Qin, Pengfei Li, Jian Wen. Hydrogen bubble growth at micro-electrode under magnetic field. Journal of Electroanalytical Chemistry 2015, 754, 22-29. https://doi.org/10.1016/j.jelechem.2015.06.015
[103]
Jakub Adam Koza, Margitta Uhlemann, Annett Gebert, Ludwig Schultz. The effect of magnetic fields on the electrodeposition of CoFe alloys. Electrochimica Acta 2008, 53, 5344-5353. https://doi.org/10.1016/j.electacta.2008.02.082
[104]
Eric F. May, Michael R. Moldover, James W. Schmidt. Electric and magnetic susceptibilities of gaseous oxygen: present data and modern theory compared. Physical Review A 2008, 78, 032522. https://doi.org/10.1103/PhysRevA.78.032522
[105]
Qizhan Zhang, Minghua Zhou, Gengbo Ren, Yawei Li, Yanchun Li, Xuedong Du. Highly efficient electrosynthesis of hydrogen peroxide on a superhydrophobic three-phase interface by natural air diffusion. Nature Communications 2020, 11, 1731. https://doi.org/10.1038/s41467-020-15597-y
[106]
Kap-Seung Choi, Jiwoong Ahn, Jungkoo Lee, Nguyen Duy Vinh, Hyung-Man Kim, Kiwon Park, Gunyong Hwang. An experimental study of scale-up, oxidant, and response characteristics in PEM fuel cells. IEEE Transactions on Energy Conversion 2014, 29, 727-734. https://doi.org/10.1109/tec.2014.2322877
[107]
Jeff T. Gostick, Michael W. Fowler, Mark D. Pritzker, Marios A. Ioannidis, Leya M. Behra. In-plane and through-plane gas permeability of carbon fiber electrode backing layers. Journal of Power Sources 2006, 162, 228-238. https://doi.org/10.1016/j.jpowsour.2006.06.096
[108]
Tatsuhiro Okada, Nobuko I. Wakayama, Liangbi Wang, Hiroshi Shingu, Jun-ich Okano, Takeo Ozawa. The effect of magnetic field on the oxygen reduction reaction and its application in polymer electrolyte fuel cells. Electrochimica Acta 2003, 48, 531-539. https://doi.org/10.1016/S0013-4686(02)00720-X
[109]
Huiyuan Zhu, Sen Zhang, Yu-Xi Huang, Liheng Wu, Shouheng Sun. Monodisperse MxFe3-xO4(M = fe, cu, co, mn) nanoparticles and their electrocatalysis for oxygen reduction reaction. Nano Letters 2013, 13, 2947-2951. https://doi.org/10.1021/nl401325u
[110]
Yuan Yuan, Zhiqiang Jiang, Minjie Li, Kun Peng. Magnetic field enhancing the electrocatalytic oxygen evolution reaction of FeMn-based spinel oxides. ACS Applied Energy Materials 2023, 6, 7865-7876. https://doi.org/10.1021/acsaem.3c00762
[111]
Olivier Devos, Omar Aaboubi, Jean-Paul Chopart, Alain Olivier, Claude Gabrielli, Bernard Tribollet. Is there a magnetic field effect on electrochemical kinetics? The Journal of Physical Chemistry A 2000, 104, 1544-1548. https://doi.org/10.1021/jp993696v
[112]
Lele Cui, Bin Chen, Dongxu Chen, Chen He, Yi Liu, Hongyi Zhang, Jian Qiu, Le Liu, Wenheng Jing, Zhenghua Zhang. Species mass transfer governs the selectivity of gas diffusion electrodes toward H2O2 electrosynthesis. Nature Communications 2024, 15, 10632. https://doi.org/10.1038/s41467-024-55091-3
[113]
Yan-Hom Li, Yen-Ju Chen. The effect of magnetic field on the dynamics of gas bubbles in water electrolysis. Scientific Reports 2021, 11, 9346. https://doi.org/10.1038/s41598-021-87947-9
[114]
Kristina Tschulik, Christian Cierpka, Annett Gebert, Ludwig Schultz, Christian J. Kähler, Margitta Uhlemann. In situ analysis of three-dimensional electrolyte convection evolving during the electrodeposition of copper in magnetic gradient fields. Analytical Chemistry 2011, 83, 3275-3281. https://doi.org/10.1021/ac102763m
[115]
Li Wang, Huijuan Yang, Juan Yang, Yixin Yang, Rongfang Wang, Shunxi Li, Hui Wang, Shan Ji. The effect of the internal magnetism of ferromagnetic catalysts on their catalytic activity toward oxygen reduction reaction under an external magnetic field. Ionics, 2016, 22, 2195-2202. https://doi.org/10.1007/s11581-016-1746-6
[116]
Yimin Chen, Xin Hu, Min Hong, Yi Zhu, Yuyu Su, Ye Fan, Zhenxiang Cheng, John Bell, Baozhi Yu, Ying Ian Chen. Magnetic field-driven catalysis: revealing enhanced oxygen reactions in Li-O2 Batteries using tailored magnetic Nanocatalysts. Advanced Science 2025, 12, 2505633. https://doi.org/10.1002/advs.202505633
[117]
Samira Siahrostami, Santiago Jimenez Villegas, Amir Hassan Bagherzadeh Mostaghimi, Seoin Back, Amir Barati Farimani, Haotian Wang, Kristin Aslaug Persson, Joseph Montoya. A review on challenges and successes in atomic-scale design of catalysts for electrochemical synthesis of hydrogen peroxide. ACS Catalysis 2020, 10, 7495-7511. https://doi.org/10.1021/acscatal.0c01641
[118]
Junying Tang, Tianshuo Zhao, Devan Solanki, Xianbing Miao, Weiguo Zhou, Shu Hu. Selective hydrogen peroxide conversion tailored by surface, interface, and device engineering. Joule 2021, 5, 1432-1461. https://doi.org/10.1016/j.joule.2021.04.012
[119]
Haifan Li, Quan Quan, Chun-Yuen Wong, Johnny C. Ho. Spin-selective catalysts for oxygen-involved electrocatalysis. Advanced Energy and Sustainability Research 2025, 6, 2400326. https://doi.org/10.1002/aesr.202400326
[120]
Adam E. Cohen. Nanomagnetic control of intersystem crossing. The Journal of Physical Chemistry A 2009, 113, 11084-11092. https://doi.org/10.1021/jp907113p
[121]
Mingyuan Yu, Erjun Kan, Cheng Zhan. The spin-coupling-dependent oxygen reduction mechanism in dual-atom catalysts. Chemical Science 2025, 16, 17753-17765. https://doi.org/10.1039/d5sc04842g
[122]
Jennifer K. Edwards, Graham J. Hutchings. Palladium and Gold-Palladium catalysts for the direct synthesis of hydrogen peroxide. Angewandte Chemie International Edition 2008, 47, 9192-9198. https://doi.org/10.1002/anie.200802818
[123]
Massimo E. Maffei. The radical pair mechanism and its quantum role in plant reactive oxygen species production under hypomagnetic fields. Quantum Reports 2025, 7, 52. https://doi.org/10.3390/quantum7040052
[124]
P. J. Hore, Henrik Mouritsen. The radical-pair mechanism of magnetoreception. Annual Review of Biophysics 2016, 45, 299-344. https://doi.org/10.1146/annurev-biophys-032116-094545
[125]
Siu Ying Wong, Philip Benjamin, P. J. Hore. Magnetic field effects on radical pair reactions: estimation of B1/2 for flavin-tryptophan radical pairs in cryptochromes. Physical Chemistry Chemical Physics 2023, 25, 975-982. https://doi.org/10.1039/d2cp03793a
[126]
Alan M. Lewis, Thomas P. Fay, David E. Manolopoulos, Christian Kerpal, Sabine Richert, Christiane R. Timmel. On the low magnetic field effect in radical pair reactions. The Journal of Chemical Physics 2018, 149, 034103. https://doi.org/10.1063/1.5038558
[127]
J. R. Woodward. Radical pairs in solution. Progress in Reaction Kinetics and Mechanism 2002, 27, 165-207. https://doi.org/10.3184/007967402103165388
[128]
Hansaem Jang, Daniel Roe, Harry E. Taylor, Emiliano Poli, Alex S. Walton, Gilberto Teobaldi, Oscar Céspedes, Alexander J. Cowan. Spin-Polarized Nonferromagnetic Surfaces for Electrocatalysis: Chemo-Spintronics. Journal of the American Chemical Society 2026, 148, 967-975. https://doi.org/10.1021/jacs.5c16824
[129]
Liu Lin, Peiyuan Su, Yiting Han, Yunming Xu, Qiao Ni, Xinyue Zhang, Peixun Xiong, Zemin Sun, Genban Sun, Xuebo Chen. Advances in regulating the electron spin effect toward electrocatalysis applications. eScience 2025, 5, 100264. https://doi.org/10.1016/j.esci.2024.100264
[130]
Zi-Shu Yang, Song Gao, Jun-Long Zhang. Magnetic manipulation of the reactivity of singlet oxygen: from test tubes to living cells. National Science Review 2024, 11, nwae069. https://doi.org/10.1093/nsr/nwae069
[131]
Evgeny M. Pliss, Aleksey M. Grobov, Anton K. Kuzaev, Anatoly L. Buchachenko. Magnetic field effect on the oxidation of organic substances by molecular oxygen. Journal of Physical Organic Chemistry 2019, 32, e3915. https://doi.org/10.1002/poc.3915
[132]
Hadi Zadeh-Haghighi, Christoph Simon. Magnetic field effects in biology from the perspective of the radical pair mechanism. Journal of The Royal Society Interface 2022, 19, 20220325. https://doi.org/10.1098/rsif.2022.0325
[133]
Tianze Wu, Jingjie Ge, Qian Wu, Xiao Ren, Fanxu Meng, Jiarui Wang, Shibo Xi, Xin Wang, Kamal Elouarzaki, Adrian Fisher, Zhichuan J. Xu. Tailoring atomic chemistry to refine reaction pathway for the most enhancement by magnetization in water oxidation. Proceedings of the National Academy of Sciences 2024, 121, e2318652121. https://doi.org/10.1073/pnas.2318652121
[134]
Adrian Schürmann, Bjoern Luerßen, Doreen Mollenhauer, Jürgen Janek, Daniel Schröder. Singlet oxygen in electrochemical cells: a critical review of literature and theory. Chemical Reviews 2021, 121, 12445-12464. https://doi.org/10.1021/acs.chemrev.1c00139
[135]
Ron Naaman, David H. Waldeck. Spintronics and chirality: spin selectivity in electron transport through chiral molecules. Annual Review of Physical Chemistry 2015, 66, 263-281. https://doi.org/10.1146/annurev-physchem-040214-121554
[136]
Ron Naaman, Yossi Paltiel, David H. Waldeck. Chiral molecules and the electron spin. Nature Reviews Chemistry 2019, 3, 250-260. https://doi.org/10.1038/s41570-019-0087-1
[137]
Karen Michaeli, Vaibhav Varade, Ron Naaman, David H Waldeck. A new approach towards spintronics-spintronics with no magnets. Journal of Physics: Condensed Matter 2017, 29, 103002. https://doi.org/10.1088/1361-648x/aa54a4
[138]
B. Göhler, V. Hamelbeck, T. Z. Markus, M. Kettner, G. F. Hanne, Z. Vager, R. Naaman, H. Zacharias. Spin selectivity in electron transmission through self-assembled monolayers of double-stranded DNA. Science 2011, 331, 894-897. https://doi.org/10.1126/science.1199339
[139]
J. K. Nørskov, T. Bligaard, J. Rossmeisl, C. H. Christensen. Towards the computational design of solid catalysts. Nature Chemistry 2009, 1, 37-46. https://doi.org/10.1038/nchem.121
[140]
Marc T.M. Koper. Thermodynamic theory of multi-electron transfer reactions: implications for electrocatalysis. Journal of Electroanalytical Chemistry 2011, 660, 254-260. https://doi.org/10.1016/j.jelechem.2010.10.004
[141]
Shih-Yun Chen, Chi-Hang Tsai, Mei-Zi Huang, Der-Chung Yan, Tzu-Wen Huang, Alexandre Gloter, Chi-Liang Chen, Hong-Ji Lin. Concentration dependence of oxygen vacancy on the magnetism of CeO2nanoparticles. The Journal of Physical Chemistry C 2012, 116, 8707-8713. https://doi.org/10.1021/jp2065634
[142]
Akshay Kumar, Mohit K. Sharma, Naveen Yadav, Ankush Vij, Manish Kumar, Seok-Hwan Huh, Jong-Woo Kim, Bon Heun Koo. Bound magnetic polarons, phonon confinement and charge transfer effects in Cr2O3/SiO2 composites. Solid State Sciences 2025, 165, 107943. https://doi.org/10.1016/j.solidstatesciences.2025.107943
[143]
Jose Gracia. Spin dependent interactions catalyse the oxygen electrochemistry. Physical Chemistry Chemical Physics 2017, 19, 20451-20456. https://doi.org/10.1039/C7CP04289B
[144]
Samuel C. Perry, Dhananjai Pangotra, Luciana Vieira, Lénárd-István Csepei, Volker Sieber, Ling Wang, Carlos Ponce de León, Frank C. Walsh. Electrochemical synthesis of hydrogen peroxide from water and oxygen. Nature Reviews Chemistry 2019, 3, 442-458. https://doi.org/10.1038/s41570-019-0110-6
[145]
Hong-bo Liu, Haotian Xu, Liang-ming Pan, Ding-han Zhong, Yang Liu. Porous electrode improving energy efficiency under electrode-normal magnetic field in water electrolysis. International Journal of Hydrogen Energy 2019, 44, 22780-22786. https://doi.org/10.1016/j.ijhydene.2019.07.024
[146]
Jingkun An, Nan Li, Qian Zhao, Yujie Qiao, Shu Wang, Chengmei Liao, Lean Zhou, Tian Li, Xin Wang, Yujie Feng. Highly efficient electro-generation of H2O2 by adjusting liquid-gas-solid three phase interfaces of porous carbonaceous cathode during oxygen reduction reaction. Water Research 2019, 164, 114933. https://doi.org/10.1016/j.watres.2019.114933
[147]
Yanfei Zhang, Qian Li, Wanchang Feng, Haotian Yue, Yichun Su, Shengjie Gao, Mohsen Shakouri, Huan Pang. Defect-dngineered metal-organic frameworks via coordination competition induction for Long-Life aqueous Zinc-Ion batteries. Angewandte Chemie International Edition 2026, e5171214. https://doi.org/10.1002/anie.5171214
[148]
Lixin Su, Chenxi Cui, Haojie Yu, Yanle Lu, Jinbing Cheng, Liqing Wu, Wenting Li, Wei Luo, Huan Pang. pH-dependent behavior of Ru-based hydrogen-oxidation electrocatalysis by a reconstructed hydrogen-bond network. Angewandte Chemie International Edition 2026, 65, e8831785. https://doi.org/10.1002/anie.8831785
[149]
Chengang Pei, Nannan Li, Xiaotong Han, Wenfeng Zhou, Xu Yu, Jin Yong Lee, Wenwu Li, Yuanhua Ding, Ho Seok Park, Huan Pang. Edge-specific confined construction of an interfacial Re-O-Co bridge for enhanced trifunctional electrocatalysis. ACS Nano 2025, 19, 17674-17685. https://doi.org/10.1021/acsnano.5c01580
[150]
Sitong Liu, Yudi Zhang, Wen Sun, Dandan Ma, Jinfu Ma, Zhiyang Wei, Juntao Huo, Dengsong Zhang, Guowei Li. Catalysis under alternating magnetic field: rethinking the origin of enhanced hydrogen evolution activities. Advanced Physics Research 2024, 3, 2300067. https://doi.org/10.1002/apxr.202300067
[151]
Jingkun Li, Jinlong Gong.Operando characterization techniques for electrocatalysis. Energy & Environmental Science 2020, 13, 3748-3779. https://doi.org/10.1039/d0ee01706j
[152]
Janis Timoshenko, Beatriz Roldan Cuenya. In situ/operando electrocatalyst characterization by X-ray absorption spectroscopy. Chemical Reviews 2021, 121, 882-961. https://doi.org/10.1021/acs.chemrev.0c00396
[153]
Jamie Y. C. Chen, Lianna Dang, Hanfeng Liang, Wenli Bi, James B. Gerken, Song Jin, E. Ercan Alp, Shannon S. Stahl. Operando analysis of NiFe and fe oxyhydroxide electrocatalysts for water oxidation: detection of Fe4+ by mössbauer spectroscopy. Journal of the American Chemical Society 2015, 137, 15090-15093. https://doi.org/10.1021/jacs.5b10699
[154]
Gerrit van der Laan, Adriana I. Figueroa. X-ray magnetic circular dichroism - a versatile tool to study magnetism. Coordination Chemistry Reviews 2014, 277-278, 95-129. https://doi.org/10.1016/j.ccr.2014.03.018
[155]
Haichuan Zhang, Yingjie Li, Hao Zhang, Guanghe Li, Fang Zhang. A three-dimensional floating air cathode with dual oxygen supplies for energy-efficient production of hydrogen peroxide. Scientific Reports 2019, 9, 1817. https://doi.org/10.1038/s41598-018-37919-3
[156]
Jinyu Zhao, Jie Lian, Zhenxin Zhao, Xiaomin Wang, Jiujun Zhang. A review of in-situ techniques for probing active sites and mechanisms of electrocatalytic oxygen reduction reactions. Nano-Micro Letters 2023, 15, 19. https://doi.org/10.1007/s40820-022-00984-5
[157]
You Hu, Junhua Chen, Zheng Wei, Qiu He, Yan Zhao. Recent advances and applications of machine learning in electrocatalysis. Journal of Materials Informatics 2023, 3, 18. https://doi.org/10.20517/jmi.2023.23
[158]
Atef El Jery, Moutaz Aldrdery, Ujwal Ramesh Shirode, Juan Carlos Orosco Gavilán, Abubakr Elkhaleefa, Mika Sillanpää Saad Sh. Sammen, Hussam H. Tizkam. An efficient investigation and machine learning-based prediction of decolorization of wastewater by using zeolite catalyst in electro-Fenton reaction. Catalysts 2023, 13, 1085. https://doi.org/10.3390/catal13071085
[159]
Feifei Li, Katlyn K. Meier, Matthew A. Cranswick, Mrinmoy Chakrabarti, Katherine M. Van Heuvelen, Eckard Münck, Lawrence Que. Characterization of a high-spin non-heme FeIII-OOH intermediate and its quantitative conversion to an FeIV═O complex. Journal of the American Chemical Society 2011, 133, 7256-7259. https://doi.org/10.1021/ja111742z
[160]
Samira Siahrostami, Arnau Verdaguer-Casadevall, Mohammadreza Karamad, Davide Deiana, Paolo Malacrida, Björn Wickman, María Escudero-Escribano, Elisa A. Paoli, Rasmus Frydendal, Thomas W. Hansen, Ib Chorkendorff, Ifan E. L. Stephens, Jan Rossmeisl. Enabling direct H2O2 production through rational electrocatalyst design. Nature Materials 2013, 12, 1137-1143. https://doi.org/10.1038/nmat3795
[161]
Christopher K. Duesterberg, T. David Waite. Process optimization of Fenton oxidation using kinetic modeling. Environmental Science & Technology 2006, 40, 4189-4195. https://doi.org/10.1021/es060311v
[162]
Yu Fan, Hao Chen, Wangxin Ge, Xiaodong Zhou, Haiyan Wang, Hongliang Jiang, Chunzhong Li. Tuning interfacial proton transfer for directing oxygen reduction reaction toward hydrogen peroxide. National Science Review 2025, 12, nwaf390. https://doi.org/10.1093/nsr/nwaf390
[163]
Stephan N. Steinmann, Qing Wang, Zhi Wei Seh. How machine learning can accelerate electrocatalysis discovery and optimization. Materials Horizons 2023, 10, 393-406. https://doi.org/10.1039/d2mh01279k
[164]
Rohit Batra, Le Song, Rampi Ramprasad. Emerging materials intelligence ecosystems propelled by machine learning. Nature Reviews Materials 2020, 6, 655-678. https://doi.org/10.1038/s41578-020-00255-y
[165]
George Em Karniadakis,Ioannis G. Kevrekidis, Lu Lu, Paris Perdikaris, Sifan Wang, Liu Yang. Physics-informed machine learning. Nature Reviews Physics 2021, 3, 422-440. https://doi.org/10.1038/s42254-021-00314-5
[166]
Toshiaki Taniike, Keisuke Takahashi. The value of negative results in data-driven catalysis research. Nature Catalysis 2023, 6, 108-111. https://doi.org/10.1038/s41929-023-00920-9
[167]
Bin-Wei Zhang, Tao Zheng, Yun-Xiao Wang, Yi Du, Sheng-Qi Chu, Zhenhai Xia, Rose Amal, Shi-Xue Dou, Liming Dai. Highly efficient and selective electrocatalytic hydrogen peroxide production on Co-O-C active centers on graphene oxide. Communications Chemistry 2022, 5, 43. https://doi.org/10.1038/s42004-022-00645-z
[168]
Rui Ding, Junhong Chen, Yuxin Chen, Jianguo Liu, Yoshio Bando, Xuebin Wang. Unlocking the potential: machine learning applications in electrocatalyst design for electrochemical hydrogen energy transformation. Chemical Society Reviews 2024, 53, 11390-11461. https://doi.org/10.1039/d4cs00844h
[169]
Donghai Huang, Tengfei Wu, Daoyue Xie, Huinan Che, Yanhui Ao. Strategies on enhancing piezocatalysis performance of ZnO-based catalysts for aquatic pollutants degradation: a review. Composite Functional Materials 2025, 1, 20250104. https://doi.org/10.63823/20250104
[170]
Shanyue He, Xin Zhang, Mei Chen, Hongquan Jiang, Yang Qu, Yanduo Liu, Jizhou Jiang. Photocatalytic H2O2 production over Ti(HPO4)2 S-scheme heterojunction through push-pull electronic effects enhance the oxygen reduction. Composite Functional Materials 2025, 1, 20250203. https://doi.org/10.63823/20250203
[171]
Yanhui Li, Changhua Wang, Qi Wu, Yuanyuan Li, Shuang Liang, Dexin Jin, He Ma, Xintong Zhang. Bronze TiO2 photocatalysis facilitates solution plasma production of H2O2. Composite Functional Materials 2025, 1, 20250204. https://doi.org/10.63823/20250204
[172]
Haoyuan Yin, Biyang Zhang, Xiaomei Dai, Jinman Yang, Jizhou Jiang, Hui Xu. 3D printing technology for photocatalysis: review and prospect. Composite Functional Materials 2025, 1, 20250205. https://doi.org/10.63823/20250205
[173]
Jing Zhang, Danni Deng, Fangqiang Wang, Yu Bai, Yuchao Wang, Yingbi Chen, Peiyao Yang, Meng Wang, Houzheng Ou, Haitao Zheng, Yongpeng Lei. Tailoring electrocatalysts for on-site H2O2 production via two electron oxygen reduction. Composite Functional Materials 2026, 2, 20260102. https://doi.org/10.63823/20260102
[174]
Hugo Olvera-Vargas, Nissim Gore-Datar, Orlando Garcia-Rodriguez, Srikanth Mutnuri, Olivier Lefebvre. Electro-Fenton treatment of real pharmaceutical wastewater paired with a BDD anode: reaction mechanisms and respective contribution of homogeneous and heterogeneous •OH. Chemical Engineering Journal 2021, 404, 126524. https://doi.org/10.1016/j.cej.2020.126524
[175]
Hugo Olvera-Vargas, Clément Trellu, Puthiya Veetil Nidheesh, Emmanuel Mousset, Soliu O. Ganiyu, Carlos A. Martínez-Huitle, Minghua Zhou, Mehmet A. Oturan. Challenges and opportunities for large-scale applications of the electro-Fenton process. Water Research 2024, 266, 122430. https://doi.org/10.1016/j.watres.2024.122430
[176]
Sumbal Farid, Jun-Hu Wang. Iron-involved ORR electrocatalysts under the lens of in situ/operando Mössbauer spectroscopy. Journal of Electrochemistry 2026, 32, 2506261. https://doi.org/10.61558/2993-074X.3578
[177]
Ju-Cai Wei, Juan Yi, Xu Wu. Electrochemical advanced treatment of desulfurization wastewater from coal-fired power plants. Journal of Electrochemistry 2024, 30, 2205041. https://doi.org/10.13208/j.electrochem.2205041
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